Bulletin of the Chemical Society of Japan p. 3781 - 3784 (1987)
Update date:2022-08-10
Topics:
Okubo, Masao
Asao, Keiko
Hyakutake, Hiroyuki
The 4-, 5-, 6-, and 7-nitro derivatives of benzothiazole condense with ArN(MgBr)2 giving unsym-azoxy and -azo products.The product distribution indicated the mild nature of the reaction, and could be explained in terms of a reduced electron-donating ability of the reagent due to an interaction with thiazolyl group.
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