Tetrahedron p. 2373 - 2380 (1983)
Update date:2022-08-29
Topics:
Davidson, R. Stephen
Goodwin, Dean
Pratt, Julie E.
The dye sensitised photo-oxidation of α-oxo-carboxylic acids and esters leads to the production of carbon dioxide.The yield of carbon dioxide is dependent upon the oxygen concentration.This, together with the fact that carbon dioxide evolution can be observed in the absence of oxygen, is in accord with the view that the decarboxylation reactions involve an initial dye-substrate interaction rather than a singlet oxygen mediated reaction.
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