Ethyl benzoylformate

Base Information

Chemical Name:Ethyl benzoylformate
CAS No.:1603-79-8
Molecular Formula:C10H10O3
Molecular Weight:178.188
Hs Code.:29183000
European Community (EC) Number:216-504-0
NSC Number:6766
UNII:AMN28N4D74
DSSTox Substance ID:DTXSID1061815
Nikkaji Number:J102.635F
Wikidata:Q27157626
Mol file:1603-79-8.mol

Synonyms:ethyl phenylglyoxylate

Suppliers and Price of Ethyl benzoylformate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Ethyl Benzoylformate
25g
$ 250.00

TCI Chemical
Ethyl Benzoylformate >96.0%(GC)
25mL
$ 70.00

TCI Chemical
Ethyl Benzoylformate >96.0%(GC)
5mL
$ 26.00

SynQuest Laboratories
Ethyl benzoylformate
50 g
$ 184.00

SynQuest Laboratories
Ethyl benzoylformate
100 g
$ 224.00

Sigma-Aldrich
Ethyl benzoylformate 95%
5g
$ 38.10

Sigma-Aldrich
Ethyl benzoylformate 95%
25g
$ 100.00

Oakwood
Ethyl Benzoylformate
25g
$ 65.00

Oakwood
Ethyl Benzoylformate
5g
$ 15.00

Oakwood
Ethyl Benzoylformate
1g
$ 10.00

Total 72 raw suppliers

Chemical Property of Ethyl benzoylformate

Chemical Property:

Appearance/Colour:clear colorless to greenish liquid
Vapor Pressure:0.0153mmHg at 25°C
Melting Point:97oC
Refractive Index:1.515-1.517
Boiling Point:256.499 °C at 760 mmHg
Flash Point:111.421 °C
PSA：43.37000
Density:1.132 g/cm³
LogP:1.43240
Storage Temp.:Store below +30°C.
Sensitive.:Moisture Sensitive
Water Solubility.:Soluble in water 1143 mg/L @ 25°C .
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:178.062994177
Heavy Atom Count:13
Complexity:192

Purity/Quality:

99% ^*data from raw suppliers

Ethyl Benzoylformate ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Chemical Classes:Other Classes -> Esters, Other
Canonical SMILES:CCOC(=O)C(=O)C1=CC=CC=C1
Uses Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts.

Technology Process of Ethyl benzoylformate

There total 186 articles about Ethyl benzoylformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 114570-16-0
(2,3-Dimethyl-benzo[g]indol-1-yl)-oxo-acetic acid ethyl ester

: phenylmagnesium bromide

: 1603-79-8
phenylglyoxylic acid ethyl ester

: 36729-21-2
2,3-dimethylbenz<6,7>indole

: 4237-46-1
α-phenylbenzoin

: 134-81-6
benzil

: 52182-15-7
ethyl benzilate

Guidance literature:: In acetone; Product distribution;
DOI:10.1007/BF00475361

Reference yield: 54.0%

: 36126-89-3
(1-hydroxy-2-oxo-2-phenylethyl)phosphonic acid diethyl ester

: 1603-79-8
phenylglyoxylic acid ethyl ester

: 65-85-0,8013-63-6
benzoic acid

Guidance literature:: With tert.-butylhydroperoxide; In toluene; at 80 ℃; for 7h; Temperature;
DOI:10.1039/c5ob01615k

Reference yield: 53.0%

: 5442-34-2
ethyl 2-phenylacetimidate hydrochloride

: 1603-79-8
phenylglyoxylic acid ethyl ester

: 101-97-3
Ethyl 2-phenylethanoate

Guidance literature:: ethyl 2-phenylacetimidate hydrochloride; With sodium hydrogencarbonate; In diethyl ether; at 0 ℃;

With pyridine; oxygen; copper diacetate; In chlorobenzene; at 90 ℃; for 20h; under 760.051 Torr; Sealed tube;

With hydrogenchloride; water; In chlorobenzene; Reagent/catalyst; Solvent; Sealed tube;
DOI:10.1021/acs.joc.6b02176