Journal of the Chemical Society - Faraday Transactions p. 3473 - 3478 (1991)
Update date:2022-08-11
Topics:
Canosa-Mas, Carlos E.
Smith, Stuart J.
Waygood, Steven J.
Wayne, Richard P.
Rate constants have been determined for the reaction of NO3 with propene from room temperature up to T = 553 K.Allowance was made in analysing experimental data for probable secondary reactions.The Arrhenius plot shows some curvature at the higher temperatures, which we suggest can be explained by the abstraction of an allylic H atom followed by chain reactions involving fast radical-radical processes.The rate constant at T = 298 K was found to be (0.93 +/- 0.12) * 10-14 cm3 molecule-1s-1.We propose the following Arrhenius expression, in units of cm3 molecule-1s-1, for the addition step in the temperature range T = 298-423 K A = 6.8*10-13 cm3molecule-1s-1 and E = 18 kJ mol-1.
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