Inorganic Chemistry p. 315 - 319 (1964)
Update date:2022-08-11
Topics:
Sullivan, James C.
A value for the equilibrium quotient Q = [Np(V)·Cr(III)]/[Np(V)][Cr(III)] of 2.62 ± 0.48 at 25° has been determined spectrophotometrically. Values of ΔH = -3.3 ± 0.6 kcal, and ΔS = -9.0 ± 1.9 e.u. have been determined. The rates of formation and aquation of the complex Np(V)·Cr(III) have been measured. The complex is also formed by the reduction of Np(VI) with Cr(II).
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