Synthesis of α-Phenylseleno Carbomethoxymethylene Triphenylarsorane and Its Wittig Type Reaction

DOI: 10.1016/0040-4039(94)02310-8

Source and publish data:

Tetrahedron Letters p. 425 - 426 (1995)

Update date:2022-08-11

Topics:

Authors:

Huang, Zhi-Zhen

Huang, Xian

Huang, Yao-Zeng

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Article abstract of DOI:10.1016/0040-4039(94)02310-8

The first example of α-seleno arsonium ylide (3) was reported.It has sufficient activity to undergo a Wittig type reaction, affording a novel method for the stereoselective synthesis of (Z)-α-seleno-α,β-unsaturated compounds (5).

Full text of DOI:10.1016/0040-4039(94)02310-8

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Product name:Acetic acid, (phenylseleno)(triphenylarsoranylidene)-, methyl ester

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