Tetrahedron Letters p. 2277 - 2280 (1998)
Update date:2022-08-11
Topics:
Ruck, Rebecca T.
Jones Jr., Maltland
Two different sources of tert-butylcarbene are used to generate this reactive intermediate in a variety of solvents. Two products, 1,1- dimethylcyclopropane and 2-methyl-2-butene are formed. Solvents able to form an ylid or complex with the carbene strongly favor the alkene product.
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