Cleavage of Both Alkyl C-H Bonds and Aryl C-F Bonds and Concomitant C-C Bond Formation in a Pentamethylcyclopentadienylrhodium Phosphine Complex: X-Ray Structure of 5-C5Me32-1,3>RhCl>+BF4-

DOI: 10.1039/c39950000191

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 191 - 192 (1995)

Update date:2022-08-11

Topics:

Authors:

Atherton, Malcolm J.

Fawcett, John

Holloway, John H.

Hope, Eric G.

Karacar, Atilla

et al. et al.

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Article abstract of DOI:10.1039/c39950000191

The reaction between bis(dipentafluorophenylphosphino)ethane, dfppe, and <<(η⁵-C5Me5)RhCl(μ-Cl)>2> proceeds with cleavage of two C-F bonds and two C-H bonds and formation of two C-C bonds to yield the ionic complex 1a.

Full text of DOI:10.1039/c39950000191

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