Tetrahedron Letters p. 3333 - 3336 (1995)
Update date:2022-08-24
Topics:
Boivin, Jean
Pillot, Eric
Williams, Alvin
Roger, Walter
Zarda, Samir Z.
Exposure of an unsaturated oxime, unsubstituted in the β-position (such as 13), to sodium nitrite-aqueous acetic acid gives an alkyne (9) through a complex series of reactions that could be mechanistically related to the conversion of an isopropylidene group into an alkyne reported a few years ago.
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