Dehydrative alkylation of alcohols with triethyl methanetricarboxylate under Mitsunobu conditions

DOI: 10.1016/0040-4020(96)00781-8

Source and publish data:

Tetrahedron p. 13007 - 13016 (1996)

Update date:2022-08-17

Topics:

Authors:

Cravotto, Giancarlo

Giovenzana, Giovanni B.

Sisti, Massimo

Palmisano, Giovanni

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Article abstract of DOI:10.1016/0040-4020(96)00781-8

Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.

Full text of DOI:10.1016/0040-4020(96)00781-8

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