A stereoselective synthesis of 1,2-disubstituted alkenyl selenides via hydroboration-iodination of internal alkylselenoacetylenes with dicyclohexylborane

DOI: 10.1016/0022-328X(96)06417-0

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 143 (1996)

Update date:2022-08-29

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Authors:

Yang, De Yu

Huang, Xian

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Article abstract of DOI:10.1016/0022-328X(96)06417-0

Selenoalkenyldicyclohexylboranes, prepared conveniently via hydroboration of internal alkylselenoacetylenes with dicyclohexylborane followed by iodination under basic conditions, produce cis/trans 1,2-disubstituted alkenyl selenides (1 and 2), which provide a general method for synthesis of cis/trans disubstituted alkenyl selenides containing a cyclohexyl group.

Full text of DOI:10.1016/0022-328X(96)06417-0

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