Tetrahedron p. 3071 - 3080 (1994)
Update date:2022-08-11
Topics:
Tedesco, Antonio C.
Naal, Rose M. Z. G.
Carreiro, Julio C.
Bonilha, Joao B. S.
Nucleophilic aromatic photosubstitution reactions of nitroaryl ethers (NArE) with sodium hydroxide were studied in aqueous solution containing N- hexadecyl-N,N,N-trimethylammonium chloride micelles. The increase of quantum yields depended on the length of the n-alkyl chain (maximum for methyl and minimum for decyl). The dependence on the surfactant concentration was in accordance with the mechanistic model of aromatic nucleophilic photosubstitution.
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(1998)
