Improved preparation of diethyl bromomethylphosphonate and diiodomethane-catalyzed triethylphosphite Michaelis-Arbuzov isomerization

Article abstract of DOI:10.1080/00397919508010806

An improved method to prepare diethyl bromomethylphosphonate and a new method for the isomerization of triethyl phosphite into diethyl ethylphosphonate are reported.

Full text of DOI:10.1080/00397919508010806

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Synthetic Communications: An
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Organic Chemistry
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Improved Preparation
of Diethyl
Bromomethylphosphonate
and Diiodomethane-Catalyzed
Triethylphosphite Michaelis-
Arbuzov Isomerization
J. Ezquerra a , B. Yruretagoyena a , M. Moreno-
Ma≁tas b & A. Roglans b
a Centro de Investigación LILLY, S.A. Department
of R&D. Paraje de la Cruz , s/n. 28130, Valdeolmos
(Madrid), Spain
b Department of Chemistry , Universitat Autònoma
de Barcelona, Bellaterra , 08193, Barcelona, Spain
Published online: 23 Sep 2006.
To cite this article: J. Ezquerra , B. Yruretagoyena , M. Moreno-Ma≁tas & A.
Roglans (1995) Improved Preparation of Diethyl Bromomethylphosphonate and
Diiodomethane-Catalyzed Triethylphosphite Michaelis-Arbuzov Isomerization,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 25:2, 191-194, DOI: 10.1080/00397919508010806
To link to this article: http://dx.doi.org/10.1080/00397919508010806
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