Scission of Ethyne into Two Methylidyne Ligands: CC vs. C-H Bond Activation

DOI: 10.1039/c39950000899

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 899 - 900 (1995)

Update date:2022-08-11

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Authors:

Adams, Harry

Gill, Louise J.

Morris, Michael J.

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Article abstract of DOI:10.1039/c39950000899

The dimolybdenum alkyne complexes 1C2R²)(η-C5H5)2> (R¹ = R² = Me; R¹ = H, R² = H, Me, Ph) react with in refluxing toluene or heptane to give the hexanuclear bis(alkylidyne) clusters 3-CR¹)(μ₃-CR²)(CO)12(η-C5H5)2>; this represents the first reported transformation of ethyne into two methylidyne ligands on a metal cluster.

Full text of DOI:10.1039/c39950000899

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