Homolytic Alkyl Group Transfer Reaction of Photoactivated Alkylcobaloximes into Thiols

DOI: 10.1021/jo00252a062

Source and publish data:

Journal of Organic Chemistry p. 4147 - 4148 (1988)

Update date:2022-08-17

Topics:

Authors:

Kijima, Masashi

Miyamori, Kiyokatsu

Sato, Takeo

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Article abstract of DOI:10.1021/jo00252a062

Alkyl groups of alkylcobaloximes were transferred to alkylthiols by irradiation of alkylcobaloxime and thiol under anaerobic conditions; a radical route via homolytic substitution between alkylcobaloxime and disulfide, formed during the reaction, is proposed.

Full text of DOI:10.1021/jo00252a062

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