Tetrahedron Letters p. 7217 - 7220 (1995)
Update date:2022-08-11
Topics:
Hendrickson, William H.
Nguyen, Chi C.
Nguyen, Jackie T.
Simons, Kim T.
Rate constants for the homolysis of aryl- substituted α-cumyl tert-butyl peroxides (X-PhCMe2OOCMe3) produce a Hammett plot with a ρ value of -0.22 +/- .04.Both steric and electronic parameters influence the decomposition rate constants of tertiary alkyl peroxides with bulky substituents: log krel = (-0.40 +/- .08)Σ?* - (0.43 +/- .02)ΣEsc.
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