
Chemical and Pharmaceutical Bulletin p. 1072 - 1074 (1992)
Update date:2022-08-18
Topics:
Yoshikawa
Murata
Yamamoto
Inoguchi
Achiwa
Using our chiral atropisomeric bisphosphines ruthenium(II) complexes, asymmetric hydrogenations of tiglic acid and its isomer were carried out. A possible enantioselective mechanism was considered on the basis of their different results on hydrogenation pressure effects.
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