Reversible C-C bond scission and C-H bond activation in the butterfly acetylide clusters Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe)

DOI: 10.1021/om00012a011

Source and publish data:

Organometallics p. 5483 - 5485 (1995)

Update date:2022-07-30

Topics:

Authors:

Chi, Yun

Su, Pei-Chiun

Peng, Shie-Ming

Lee, Gene-Hsiang

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Article abstract of DOI:10.1021/om00012a011

The tetranuclear acetylide compounds Cp*WOs₃(CO)₁₁(CCR) (R = Ph, Bu, CH₂OMe), depending on the substituents of the acetylide ligand, undergo reversible C-C bond scission and C-H activation to afford the carbido-alkylidyne

Full text of DOI:10.1021/om00012a011

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