Tetrahedron Letters p. 3877 - 3880 (1993)
Update date:2022-08-11
Topics:
Brunet
Neibecker
Philippot
The system generated from lithium anilide and [(Et3P)2RhCl]2 caralyzes (turnover 21) the regioselective condensation of aniline with styrene to give a mixture of PhNH-CH(CH3)Ph (hydroamination product) and PhN=C(CH3)Ph (oxidative hydroamination product) in c.a. 1/2 ratio. This 100% regioselective oxidative hydroamination has been confirmed in the case of 1-hexene.
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