Tetrahedron Letters p. 1783 - 1786 (1996)
Update date:2022-08-11
Topics:
Diziere, Rachel
Savignac, Philippe
1-Alkynylphosphonates 4 were obtained from (EtO)2P(O)CCl3 1 and aldehydes in a one-pot procedure. It involves the formation of α-chlorovinyl phosphonate intermediates 3 by a Peterson olefination reaction followed by dehydrochlorination with LiHMDS.
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