Tetrahedron Letters p. 6677 - 6680 (1994)
Update date:2022-08-10
Topics:
Cruciani, Paul
Aubert, Corinne
Malacria, Max
Cobalt(I) catalyzed cycloisomerization of a ε-acetylenic β'-alkyl β-ketoester led to highly functionalized methylenecyclopentanes with stereocontrol of two contiguous centers.The level of diastereoselectivity is moderate to high (de = 12-92percent).
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