Journal of the Chemical Society. Perkin transactions II p. 445 - 447 (1991)
Update date:2022-08-17
Topics:
Burdon, James
Creasey, Jeremy C.
Proctor, Lee D.
Plevey, Raymond G.
Yeoman, J.R. Neil
Perfluorination of hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, 2,3-dimethylbutane, methylcyclopentane and cyclohexane over cobalt(III) trifluoride gave, in each case except perhaps cyclohexane, a mixture of linear, branched and cyclic C6-fluorocarbons: the degree of skeletal rearrangement (excluding cyclohexane) varied from ca. 7percent (methylcyclopentane) to 96percent (2,2-dimethylbutane).A carbocation mechanism, which does not proceed to equilibrium, is suggested.
View MoreShanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Shanghai Yuantai Chemical Products Co., Ltd
Contact:021--66129803
Address:Chengyin Road,Shanghai,China
Contact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Contact:86-574-26865651
Address:529 YuanBaoShan Road, Beilun District
Contact:021
Address:Pudong
Doi:10.1016/0021-9517(89)90219-4
(1989)Doi:10.1134/S1070428010050039
(2010)Doi:10.1002/hlca.19430260616
(1943)Doi:10.1016/S0040-4039(00)80578-X
(1988)Doi:10.1023/A:1023979230025
(2003)Doi:10.1016/S0022-328X(00)83178-2
(1967)
