Journal of the Chemical Society. Perkin transactions II p. 445 - 447 (1991)
Update date:2022-08-17
Topics:
Burdon, James
Creasey, Jeremy C.
Proctor, Lee D.
Plevey, Raymond G.
Yeoman, J.R. Neil
Perfluorination of hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, 2,3-dimethylbutane, methylcyclopentane and cyclohexane over cobalt(III) trifluoride gave, in each case except perhaps cyclohexane, a mixture of linear, branched and cyclic C6-fluorocarbons: the degree of skeletal rearrangement (excluding cyclohexane) varied from ca. 7percent (methylcyclopentane) to 96percent (2,2-dimethylbutane).A carbocation mechanism, which does not proceed to equilibrium, is suggested.
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