(4-Chlorobenzenethiolato-S)(η5-cyclopentadienyl) (triphenylphosphine-P)nickel(II)

Article abstract of DOI:10.1107/S0108270196005896

The Ni atom in [Ni(C₆H₄ClS)(C₅H₅)(C₁₈H₁₅P)] has a distorted trigonal geometry, with bond angles Cp - Ni - S Ni - S 132.3 (1), Cp - Ni - P 135.3 (5) and P - Ni - S 92.4 (1)°, where Cp represents the controid of the C₅H₅ ring. The bond distances Cp - Ni, Ni - S and Ni - P are 1.763 (1), 2.190 (1) and 2.144 (1) angstrom, respectively, which are close to distances found in similar compounds. A structural model with disordered cyclopentadienyl ligands was used.