Spectroscopic and Kinetic Study of an Intramolecular Aromatic Nucleophilic Photosubstitution. Reaction Mechanism of a Photo-Smiles Rearrangement

DOI: 10.1246/bcsj.53.2472

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2472 - 2475 (1980)

Update date:2022-08-11

Topics:

Authors:

Yokoyama, Kenji

Nakagaki, Ryoichi

Nakamura, Junko

Mutai, Kiyoshi

Nagakura, Saburo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.53.2472

Photo-Smiles rearrangement reaction of N-<ω-(p-nitrophenoxy)alkyl>aniline was studied by measuring the absorption spectra of transient species.Two intermediates A and B were observed and were assigned to a solvated ion pair and the Meisenheimer complex, r

Full text of DOI:10.1246/bcsj.53.2472

Products guided by the article

Product name:Ethanol, 2-[(4-nitrophenyl)phenylamino]-

Cas No:18226-18-1

R&D Labs maybe for 18226-18-1

Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Jiangsu Feymer Technology Co., Ltd.

Contact:+86-512-58110132

Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China

Relevant to this article

Doi:10.1016/0021-9517(73)90048-1
(1973)
Direct electrochemistry of glucose oxidase and sensing of glucose at a glassy carbon electrode modified with a reduced graphene oxide/fullerene-C60 composite

Doi:10.1039/c5ra12018g
(2015)
A New Synthesis of trans-Iodohydrins using Iodine-Cerium(IV) Salts

Doi:10.1039/a605548f
(1997)
A convenient, one-pot procedure for the preparation of acyl and sulfonyl fluorides using Cl₃CCN, Ph₃P, and TBAF(t -BuOH) ₄

Doi:10.1055/s-0030-1259051
(2010)
Effective Strategy for High-Yield Furan Dicarboxylate Production for Biobased Polyester Applications

Doi:10.1021/acscatal.9b00450
(2019)
Halisphingosines A and B, modified sphingoid bases from Haliclona tubifera. Assignment of configuration by circular dichroism and van't Hoff's principle of optical superposition

Doi:10.1021/np300744y
(2013)

Article Doi