Stereocontrolled synthesis of α-C-galactosamine derivatives promoted by samarium diiodide: An example of chelation controlled C-glycosylation

DOI: 10.1039/CC9960001883

Source and publish data:

Chemical Communications p. 1883 - 1884 (1996)

Update date:2022-08-30

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Authors:

Urban, Dominique

Skrydstrup, Troels

Riche, Claude

Chiaroni, Angele

Beau, Jean-Marie

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Article abstract of DOI:10.1039/CC9960001883

Direct coupling of the pyridylsulfone of N-acetylgalactosamine with aldehydes or ketones is promoted by samarium diiodide unexpectedly giving the corresponding α-C-glycosides.

Full text of DOI:10.1039/CC9960001883

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