Molecular Structure and Carbonylation of Ethyl(benzenethiolato)palladium(II) Complex, trans-PdEt(SPh)(PMe3)2

DOI: 10.1246/bcsj.64.2002

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Bulletin of the Chemical Society of Japan p. 2002 - 2004 (1991)

Update date:2022-08-11

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Authors:

Osakada, Kohtaro

Ozawa, Youichi

Yamamoto, Akio

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Article abstract of DOI:10.1246/bcsj.64.2002

X-Ray crystallography of ethylpalladium thiolato complex, trans-PdEt(SPh)(PMe3)2, shows the detailed features of the Pd-C and Pd-S bonding.Reaction of the complex with CO at 5 atm gives S-phenyl thiopropionate.The NMR spectrum of the reaction mixture unde

Full text of DOI:10.1246/bcsj.64.2002

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