Helvetica Chimica Acta p. 1643 - 1650 (1996)
Update date:2022-08-11
Topics:
Hasenknopf, Bernold
Lehn, Jean-Marie
The synthesis of the linear tris[terpyridine] 1 with three tridentate binding sites is described. The reaction with metal ions of octahedral coordination geometry, such as FeII or NiII, leads to the self-assembly of trinuclear complexes [M3(I)2]6+, which display properties in agreement with a double helical structure. The trinuclear iron(II) helicate has been resolved into its enantiomers.
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(1996)