Journal of Organic Chemistry p. 8453 - 8455 (1996)
Update date:2022-08-11
Topics:
Gendre, Pierre Le
Braun, Thomas
Bruneau, Christian
Dixneuf, Pierre H.
The enantioselective hydrogenation of α-methylene-1,3-dioxolan-2-ones catalyzed by chiral (diphosphine)ruthenium complexes leads to optically active cyclic carbonates with high enantioselectivities.Their hydrolysis in methanol in the presence of potassium carbonate quantitatively affords optically active 1,2-diols.
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