Methyleniminium salts as acylating agent - One step synthesis of baccatin III from 10-deacetylbaccatin III with high selectivity

DOI: 10.1016/S0040-4039(98)00699-6

Source and publish data:

Tetrahedron Letters p. 4263 - 4266 (1998)

Update date:2022-08-16

Topics:

Authors:

Cravallee, Christelle

Didier, Eric

Pecquet, Pascal

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Article abstract of DOI:10.1016/S0040-4039(98)00699-6

New methyleniminium salts were investigated as acylating agent of 10- deacetylbaccatin III. Thus, synthesis of baccatin III was performed in one step with 79% isolated yield and 98% selectivity using the iminium salt and from mesyl chloride and N-ethylacetamide.

Full text of DOI:10.1016/S0040-4039(98)00699-6

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