Journal of the Chemical Society. Chemical communications p. 1233 - 1234 (1980)
Update date:2022-08-16
Topics:
Miyano, Sotaro
Tobita, Masayuki
Nawa, Masayoshi
Sato, Shinya
Hashimoto, Harukichi
Intramolecular Ullmann coupling of (S)-2,2'-bis-(1-bromo-2-naphthylcarbonyloxy)-1,1'-binaphthyl <(S)-(1)> induced axial dissymmetry of the S-configuration into the newly formed 1,1'-binaphthyl linkage affording (S,S)-tetranaphtho<2,1-b; 1,2-d; 2,1-h; 1,2-j><1,6>dioxacyclododecene-11,16-dione <(SS)-(2)> with virtually complete diastereoselectivity.
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