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THE HYDROLYSIS OF DIBROMOFLUOROMETHYLTRIPHENYLPHOSPHONIUM BROMIDE

DOI: 10.1016/S0022-1139(00)81522-5

Source and publish data:

Journal of Fluorine Chemistry p. 371 - 376 (1982)

Update date:2022-08-11

Topics:

Authors:

Burton, Donald J.Burton, Donald J.

Flynn, R. M.Flynn, R. M.

Manning, R. G.Manning, R. G.

Kessler, R. M.Kessler, R. M.

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Article abstract of DOI:10.1016/S0022-1139(00)81522-5

Hydrolysis of Br(1-) afforded a high yield of dibromofluoromethane and triphenylphosphine oxide.Hydrolysis in the presence of a radioactive isotope of bromine gave evidence that the mechanism of this reaction proceeds via the dibromofluoromethide ion and not via a bromofluorocarbene intermediate.

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Full text of DOI:10.1016/S0022-1139(00)81522-5

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