A new convenient method for the high-yield synthesis of Ir4(CO)12

DOI: 10.1016/0022-328X(90)87129-2

Source and publish data:

Journal of Organometallic Chemistry p. 381 - 383 (1990)

Update date:2022-08-10

Topics:

Authors:

Pruchnik, F. P.

Wajda-Hermanowicz, K.

Koralewicz, M.

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Article abstract of DOI:10.1016/0022-328X(90)87129-2

The complex Ir4(CO)12 has been prepared by a new, simple method, involving heating of solutions of Ir^III or Ir^IV chlorides in 98percent formic acid.Reaction at 100 deg C gave pure Ir4(CO)12 in 100percent yield.

Full text of DOI:10.1016/0022-328X(90)87129-2

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