Applied Catalysis A: General p. 37 - 42 (2019)
Update date:2022-08-17
Topics:
Lorenti, Juliana P.
Scolari, Eduardo
Albuquerque, Elise M.
Fraga, Marco A.
Gallo, Jean Marcel R.
Sn-SBA-15 was prepared by different methods seeking to tailor its catalytic properties. The effect of the SBA-15 synthesis pH and Sn loading in the Sn-SBA-15 structure, porosity, and type of generated Sn species on catalyst activity towards glucose isomerization was systematically evaluated. Increasing the acid concentration and the Sn loading led to a bimodal distribution of the unit cell parameter. Surface area, pore volume, and microporosity formation was not significantly affected by the synthesis parameter, while the distribution of the large mesopores was. Indeed, the catalysts with broad size distribution presented lower TON for fructose formation compared to the ones with narrow distribution. The catalytic activity was also shown to be dependent on the nature of the solvent, and initial TOF for fructose formation increased as methanol < THF < GVL.
View MoreAngelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Shanghai Longjin Metallic Material Co., Ltd.
website:http://www.shlongjin.cn/
Contact:021-56517503,56502257
Address:No.16, Lane 555, Chengyin Road, Shanghai
Hangzhou Mole's Science & Technology Co.,Ltd.
Contact:+86-571-56880228
Address:15F Guodu development Building, NO.182 Zhaohui Road
Xiamen Hisunny Chemical Co.,Ltd
website:http://www.hisunnychem.com
Contact:+86-592-3327115
Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Shandong Xinhua Pharmaceutical Co.,Ltd
website:http://www.xhzy.com
Contact:+86-533-2196801
Address:1 lutai road,zhangdian dis,Zibo City
Doi:10.1016/0031-9422(91)85243-S
(1991)Doi:10.1007/s10534-020-00267-9
(2021)Doi:10.3390/md13084915
(2015)Doi:10.1080/00397910902883579
(2009)Doi:10.1021/ja00901a034
(1963)Doi:10.1021/acs.organomet.6b00023
(2016)