Synthetic Communications p. 29 - 41 (2003)
Update date:2022-08-17
Topics:
Hailes, Helen C.
Isaac, Ben
Javaid, M. Hashim
The syntheses of 2-butyl-4,5-dimethylcyclopent-4-ene-1,3-dione, possessing a buttery jasmine odor, and a series of analogues have been carried out via the synthesis of butenolactones, with subsequent conversion to 4,5-dimethylcyclopent-4-ene-1,3-dione and an alkylation strategy. The compound with the strongest odor characteristics, has also been synthesised using a Pauson-Khand reaction and selective oxidative route.
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