Diels-Alder Reaction of Chiral Acrylamide and a Convenient Synthesis of Optically Pure Methyl (3R, 4R, 6R)-Bicycloheptene-4-carboxylate

DOI: 10.1246/cl.1988.1623

Source and publish data:

Chemistry Letters p. 1623 - 1624 (1988)

Update date:2022-08-23

Topics:

Authors:

Kishikawa, Keieki

Yamamoto, Makoto

Kohmoto, Shigeo

Yamada, Kazutoshi

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Article abstract of DOI:10.1246/cl.1988.1623

Asymmetric Diels-Alder reaction of the chiral acrylamide 1 proceeds highly diastereoselectively and methanolysis of the adduct 2 gives the optically pure (3R, 4R, 6R)-bicyclo<2. 2. 1>heptene-4-carboxylate.

Full text of DOI:10.1246/cl.1988.1623

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