Journal of the Chemical Society. Perkin transactions II p. 1329 - 1332 (1988)
Update date:2022-08-22
Topics:
Chandra, Harish
Bathgate, Antoinette
Malpass, John R.
Moss, Richard E.
Symons, Martyn C. R.
Exposure of dilute solutions of various dialkyl and cyclic N-chloro amines in trichlorofluoromethane to (60)Co γ-rays at 77 K gave the corresponding cations, R2N.Cl, characterised by (14)N, (35)Cl, and (1)H hyperfine coupling.The results suggest that these radicals are essentially planar at nitrogen, the SOMO being the N-Cl ?* orbital.Similar treatment of dilute solutions in methanol or methyltetrahydrofuran gave the corresponding amino radicals, R2N., also characterised by their e.s.r. spectra.There was no evidence for the formation of the parent radical anions.These results are contrasted with those for N-halogeno imides and the formation of ?* radicals from the cations R3N. and halide ions.
View MoreContact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)
website:http://www.bjgreenchem.com/
Contact:+86-427-6515887
Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）
Contact:86-531-88072280
Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China
Jiangxi Dongbang Pharmaceutical Co., Ltd.
Contact:+86-795-4433603, 4433388
Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Shanghai Minstar Chemical Co., Ltd
website:http://www.minstargroup.com
Contact:86-21-18019205509
Address:BUILDING 8, NO.1098, CHUANSHA ROAD, SHANGHAI, CHINA
Doi:10.14233/ajchem.2017.20623
(2017)Doi:10.1023/A:1026068327516
(2003)Doi:10.1080/00397911.2021.1927098
(2021)Doi:10.1021/jo00945a026
(1973)Doi:10.1021/acs.orglett.0c02281
(2020)Doi:10.1002/chem.201102627
(2011)
