Tetrahedron Letters p. 5389 - 5392 (1995)
Update date:2022-08-11
Topics:
Wijnen, Jan W.
Steiner, Roberto A.
Engberts, Jan B. F. N.
Second-order rate constants for the cycloaddition of phenyl azide to norbomene were determined in aqueous solutions. In organic solvents this reaction shows a very small solvent effect. In highly aqueous media, however, remarkable accelerations are observed. The solvent dependence of the rate constants on solvent composition in mixed aqueous solutions resembles those observed for Diels-Alder reactions, most likely because both types of cycloadditions are mechanistically related.
View More
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
Lishui Nanming Chemical Co., Ltd(expird)
Contact:+86-0578-2134101，2697830
Address:No.19 Tongji Road Shuige Industrial zone
KINHENG CHEMICAL(SHANGHAI)CO., LTD.
Contact:+8621-60490170
Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Wuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Zhejiang Chemicals Import & Export Corporation
Contact:86-571-87043088
Address:No.37,Qingchun Road,Hangzhou,China
Doi:10.1016/S0040-4039(00)85631-2
(1982)Doi:10.1016/S0040-4039(99)01437-9
(1999)Doi:10.1023/A:1018538424373
(1997)Doi:10.1002/macp.1963.020670112
(1963)Doi:10.1016/S0040-4039(99)00346-9
(1999)Doi:10.1016/0025-5408(94)00141-3
(1995)
