
Journal of the Chemical Society - Faraday Transactions p. 2599 - 2602 (1991)
Update date:2022-08-16
Topics:
Gritzner, Gerhard
Lewandowski, Andrzej
Temperature coefficients of polarographic half-wave potentials for Li+, Na+, K+, Rb+, Cs+, Tl+, Cu2+, Zn2+, Cd2+, Ba2+, Pb2+, bis(biphenyl)chromium(I) tetraphenylborate, ferrocene and perylene have been derived from measurements vs.Ag/Ag+ (0.01 mol dm-3) electrodes kept at 25 deg C in 0.1 mol dm-3 solutions of tetrabutylammonium perchlorate in dimethyl sulphoxide, N,N-dimethylformamide, hexamethylphosphoric triamide and propylene carbonate.Entropies for the above mentioned redox couples and for Ag+ were calculated for reversible electrode reactions on the basis of the assumption of a negligible thermal diffusion potential.This assumption was also employed to calculate single-ion entropies of transfer from N,N-dimethylformamide into dimethyl sulphoxide, propylene carbonate and hexamethylphosphoric triamide.
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