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Geometrically directed selective steroid hydroxylation with high turnover by a fluorinated artificial cytochrome P-450

DOI: 10.1016/S0040-4039(98)00425-0

Source and publish data:

Tetrahedron Letters p. 2887 - 2890 (1998)

Update date:2022-08-17

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Authors:

Breslow, RonaldBreslow, Ronald

Gabriele, BartoloGabriele, Bartolo

Yang, JerryYang, Jerry

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Article abstract of DOI:10.1016/S0040-4039(98)00425-0

A metalloporphyrin has been synthesized carrying a beta-cyclodextrin group on tetrafluorophenyl rings at the four meso positions of the porphyrin. It performs the selective hydroxylation of an androstanediol derivative with complete positional selectivity

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Full text of DOI:10.1016/S0040-4039(98)00425-0

Products guided by the article

Product name:3-(4-tert-Butyl-phenyl)-4-(2-sulfo-ethylcarbamoyl)-butyric acid (3S,5S,6S,8R,9S,10R,13S,14S,17S)-17-[3-(4-tert-butyl-phenyl)-4-(2-sulfo-ethylcarbamoyl)-butyryloxy]-6-hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yl ester

Cas No:198560-58-6

198560-58-6

R&D Labs maybe for 198560-58-6

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