
Journal of Organic Chemistry p. 2124 - 2128 (1985)
Update date:2022-08-11
Topics:
Ewing, James C.
Ferguson, Gregory S.
Moore, Douglas W.
Schultz, Frederick W.
Thompson, David W.
The reactions of homopropargyl alcohols with titanium tetrachloride-trimethylaluminum in methylene chloride under mild conditions selectively yield after hydrolysis alkenols of the type HOCH(R)CH2CH=C(R')CH3, R =H, Me, and Et and R'= H, Me, Et, n-Pr, i-Pr, n-C4H9, n-C5H11, and Ph.
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Doi:10.1021/j100036a037
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(1989)