Tetrahedron p. 339 - 348 (1985)
Update date:2022-08-10
Topics:
Dunkin, Ian R.
Bell, Gordon A.
The photolysis of diazoindene and diazofluorene at 12 K in N2 matrices containing O2 has been studied, using i.r. spectroscopy.The carbonyl oxides, indenone O-oxide and fluorenone O-oxide, were formed by the reaction of O2 with the corresponding carbenes, and under appropriate conditions could be detected as very photolabile species.Photolysis of indenone O-oxide gave indenone and isocoumarin; similar photolysis of fluorenone O-oxide gave fluorenone and dibenzopyran-6-one.
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