Enthalpies of combustion of 2,4,6-trimethylbenzonitrile, 2,4,6-trimethylbenzonitrile N-oxide, 2,6-dimethylbenzonitrile, 2,4,6-trimethoxybenzonitrile, and 2,4,6-trimethoxybenzonitrile N-oxide: the dissociation ethalpies of the (N-O) bonds

Article abstract of DOI:10.1016/S0021-9614(05)80055-2

The standard (p^deg = 0.1 MPa) molar enthalpies of combustion at 298.15 K were measured by static-bomb calorimetry and the standard molar enthalpies of sublimation at 298.15 K were measured by microcalorimetry for the following aromatic nitriles and aromatic nitrile N-oxides:

.From the standard molar enthalpies of formation of the gaseous compounds, the molar dissociation enthalpies of the (N-O) bonds were derived: D(N-O)/(kJ*mol^-1): trimethylbenzonitrile N-oxide, (222.2 +/- 4.6); trimethoxybenzonitrile N-oxide, (232.8 +/- 3.8).

Full text of DOI:10.1016/S0021-9614(05)80055-2

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