Oxygen Atom Transfer in the Oxidation of Triphenylphosphine by μ-Oxo-bis

DOI: 10.1039/c39830000549

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 549 - 550 (1983)

Update date:2022-08-11

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Authors:

Ercolani, Claudio

Gardini, Marcello

Pennesi, Giovanna

Rossi, Gentilina

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Article abstract of DOI:10.1039/c39830000549

It has been shown that μ-oxo-bis can oxidize triphenylphosphine to triphenylphosphine oxide in the presence of pyridine under mild conditions, resulting in the formation of the corresponding Fe^II-bis adduct; this reaction is a rare example of O atom transfer by a μ-oxo Fe^III oligomer.

Full text of DOI:10.1039/c39830000549

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