Molybdenum(II)-catalyzed alkylation of electron-rich aromatics with allylic acetates

DOI: 10.1016/S0040-4039(97)01053-8

Source and publish data:

Tetrahedron Letters p. 4899 - 4902 (1997)

Update date:2022-08-17

Topics:

Authors:

Malkov, Andrei V.

Davis, Stuart L.

Mitchell, William L.

Kocovsky, Pavel

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)01053-8

The molybdenum(II) complex [Mo(CO)₄Br₂]₂ has been found to catalyze allylic substitution with aromatic ethers, e.g., anisole (7), as nucleophiles. The reaction is remarkably para-selective (e.g. 7 + 8 → 11).

Full text of DOI:10.1016/S0040-4039(97)01053-8

Products guided by the article

Product name:Benzene, 1-methoxy-4-(3-phenyl-2-propenyl)-

Cas No:20442-73-3

R&D Labs maybe for 20442-73-3

Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
ChengduChroma-BiotechCo.,Ltd.

Contact:86-28-61993785

Address:No.70-13-21, North Section, Erhuan
Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing

Relevant to this article

Structure, magnetism and reactivity of a {Mn^III(μ-O)₂Mn^IV}³⁺ core towards oxidation of phenols

Doi:10.1016/j.poly.2019.06.032
(2019)
Effect of an Inefficient Electron Scavenger on Infrared- and Visible-Absorbing Electrons in an Ethanol Matrix

Doi:10.1021/j100438a014
(1980)
CARBONYLATION OF ACETALDEHYDE ON ION-EXCHANGE CATALYSTS

Doi:10.1007/BF00950176
(1985)
Conductivity enhancement and thermal properties of AgI-MO₂ (M = Zr, Si) Composites using sol-gel derived aerogels

Doi:10.1149/1.1475687
(2002)
Synthesis of (S)-3-amino-benzo[b][1,4]oxazepin-4-one via Mitsunobu and S_NAr reaction for a first-in-class RIP1 kinase inhibitor GSK2982772 in clinical trials

Doi:10.1016/j.tetlet.2017.05.001
(2017)
TEDETA@BNPs as a basic and metal free nanocatalyst for Knoevenagel condensation and Hantzsch reaction

Doi:10.1007/s13738-018-1417-9
(2018)

Article Doi