Tetrahedron Letters p. 4899 - 4902 (1997)
Update date:2022-08-17
Topics:
Malkov, Andrei V.
Davis, Stuart L.
Mitchell, William L.
Kocovsky, Pavel
The molybdenum(II) complex [Mo(CO)4Br2]2 has been found to catalyze allylic substitution with aromatic ethers, e.g., anisole (7), as nucleophiles. The reaction is remarkably para-selective (e.g. 7 + 8 → 11).
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