C-H Allylic Bond Cleavage to generate an Active Hydridopalladium Species for the Alkoxycarbonylation of Alkenes. X-Ray Crystal Structure of

DOI: 10.1039/c39930000747

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Journal of the Chemical Society. Chemical communications p. 747 - 750 (1993)

Update date:2022-08-11

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Authors:

Chenal, Thomas

Naigre, Ruth

Cipres, Isabelle

Kalck, Philippe

Daran, Jean-Claude

Vaissermann, Jacqueline

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Article abstract of DOI:10.1039/c39930000747

On the basis of a reactivity study using various alkenes and of the X-ray crystal structure analysis of the title compound isolated from the alkoxycarbonylation reaction, the formation of an active Pd(H)(SnCl3) species, generated from the SnCl2-PPh3 system, is proposed.

Full text of DOI:10.1039/c39930000747

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