Mendeleev Communications p. 143 - 144 (2010)
Update date:2022-08-29
Topics:
Lyubimov, Sergey E.
Kuchurov, Ilya V.
Vasil'Ev, Andrei A.
Zlotin, Sergei G.
Davankov, Vadim A.
P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO2 pressures and structure of catalysts.
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