Single Electron Transfer Induced Total Synthesis of Canthin-6-one

DOI: 10.1016/S0040-4039(99)01472-0

Source and publish data:

Tetrahedron Letters p. 7075 - 7078 (1999)

Update date:2022-08-29

Topics:

Authors:

Roessler, Ulrich

Blechert, Siegfried

Steckhan, Eberhard

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Article abstract of DOI:10.1016/S0040-4039(99)01472-0

The cytotoxic alkaloid canthin-6-one was synthesized from harmalane in a short sequence (six steps) with good overall yield (18 percent) using a single electron transfer (SET) induced radical cationic hetero [4+2] cycloaddition as high yielding key step.

Full text of DOI:10.1016/S0040-4039(99)01472-0

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