A "TUNABLE" STEREOSELECTIVE ALKENE SYNTHESIS BY IODODESILYLATION OF VINYLSILANES

DOI: 10.1016/S0040-4039(00)84127-1

Source and publish data:

Tetrahedron Letters p. 883 - 886 (1986)

Update date:2022-08-11

Topics:

Authors:

Chan, T. H.

Koumaglo, K.

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Article abstract of DOI:10.1016/S0040-4039(00)84127-1

The stereoselectivity of iododesilylation of terminal E-vinylsilanes varies with changing amount of Lewis acid.The use of this "tunable" stereoselective reaction was demonstrated by the syntheses of two insect sex pheromones with defined E/Z isomeric rations.

Full text of DOI:10.1016/S0040-4039(00)84127-1

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