PHOTOISOMERIZATION OF 3-BENZOYLACRYLATES ON A SILCA GEL SURFACE: EFFECT OF REACTION ENVIRONMENT ON SELECTIVITY

DOI: 10.1002/poc.610080107

Source and publish data:

Journal of Physical Organic Chemistry p. 31 - 34 (1995)

Update date:2022-08-30

Topics:

Authors:

Hasegawa, Tadashi

Yamazaki, Yuko

Yoshioka, Michikazu

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Article abstract of DOI:10.1002/poc.610080107

On irradiation on a dry silica gel surface, 2-(N,N-dialkylamino)ethyl 3-benzoylacrylates undergo selective E-Z isomerization.Competing processes, such as remote-hydrogen abstraction via a charge-transfer state, with the photoisomerization in solution are

Full text of DOI:10.1002/poc.610080107

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