Tetrahedron Letters p. 5775 - 5778 (1996)
Update date:2022-08-12
Topics:
Akhrem, Irena
Churilova, Irina
Bernadyuk, Stanislav
Vol'pin, Mark
The reaction of adamantane with carbon monoxide at -45°/+20°C over 0.5-2 h, catalyzed by the aprotic organic superacid CBr4·2AlBr3, is described. The formylation of adamantane under CO atmosphere at 0/+20°C in the presence of methylcyclopentane as a source of hydride ion affords 1-adamantanecarbaldehyde (1) in yield 70-72% on adamantane for 1 h.
View More
Contact:+86-571-87010026
Address:202, Zhenhua Road,
Contact:021-50278900
Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Suzhou Chiral Pharmaceuticals Co., Ltd.
Contact:86-0512-63197058
Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
BAODING SINO-CHEM INDUSTRY CO.,LTD
Contact:0312-5956088
Address:NO.8 FUXING ROAD,CHINA
Contact:+86-531-58668191 58668193 58668196 58661173
Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Doi:10.1246/bcsj.82.613
(2009)Doi:10.1039/d0nj00887g
(2020)Doi:10.1021/ol035020v
(2003)Doi:10.1021/jo00174a040
(1983)Doi:10.1002/aoc.6225
(2021)Doi:10.1039/tf9575300800
(1957)
