An effective formylation of adamantane with CO initiated by the aprotic organic superacid CBr4·2AlBr3 under mild conditions

DOI: 10.1016/0040-4039(96)01223-3

Source and publish data:

Tetrahedron Letters p. 5775 - 5778 (1996)

Update date:2022-08-12

Topics:

Authors:

Akhrem, Irena

Churilova, Irina

Bernadyuk, Stanislav

Vol'pin, Mark

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01223-3

The reaction of adamantane with carbon monoxide at -45°/+20°C over 0.5-2 h, catalyzed by the aprotic organic superacid CBr₄·2AlBr₃, is described. The formylation of adamantane under CO atmosphere at 0/+20°C in the presence of methylcyclopentane as a source of hydride ion affords 1-adamantanecarbaldehyde (1) in yield 70-72% on adamantane for 1 h.

Full text of DOI:10.1016/0040-4039(96)01223-3

Products guided by the article

Product name:Ethyl adamantane-1-carboxylate

Cas No:2094-73-7

R&D Labs maybe for 2094-73-7

JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Shandong Xingshun New Material Co., Ltd.

website:http://www.sd-xingshun.com

Contact:+86-519-86461196/+86-519-86464994

Address:Middle of Luhua East Road, Dingtao District
Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China

Relevant to this article

Photochemical reactions in nanoscopic organic domains generated from oriented crystalswith polymers: Nanocrystalline mosaics as a new familyof host materials

Doi:10.1246/bcsj.82.613
(2009)
Rapid abnormal [3+2]-cycloaddition of isatinN,N′-cyclic azomethine imine 1,3-dipoles with chalcones

Doi:10.1039/d0nj00887g
(2020)
Novel one-pot vicinal double C-acylation of styrenes and methacrylates by electroreduction

Doi:10.1021/ol035020v
(2003)
Mechanism of Bromination of 1,5-Diacetoxynaphthalene

Doi:10.1021/jo00174a040
(1983)
New advances in catalytic performance of erbium-folic acid-coated CoFe₂O₄ complexes for green one-pot three-component synthesis of pyrano[2,3-d]pyrimidinone and dihydropyrano[3,2-c]chromenes compounds in water

Doi:10.1002/aoc.6225
(2021)
Doi:10.1039/tf9575300800
(1957)

Article Doi