An effective formylation of adamantane with CO initiated by the aprotic organic superacid CBr4·2AlBr3 under mild conditions

DOI: 10.1016/0040-4039(96)01223-3

Source and publish data:

Tetrahedron Letters p. 5775 - 5778 (1996)

Update date:2022-08-12

Topics:

Authors:

Akhrem, Irena

Churilova, Irina

Bernadyuk, Stanislav

Vol'pin, Mark

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Article abstract of DOI:10.1016/0040-4039(96)01223-3

The reaction of adamantane with carbon monoxide at -45°/+20°C over 0.5-2 h, catalyzed by the aprotic organic superacid CBr₄·2AlBr₃, is described. The formylation of adamantane under CO atmosphere at 0/+20°C in the presence of methylcyclopentane as a source of hydride ion affords 1-adamantanecarbaldehyde (1) in yield 70-72% on adamantane for 1 h.

Full text of DOI:10.1016/0040-4039(96)01223-3

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